Changing seas in the Early–Middle Miocene of Central Europe: a Mediterranean approach to Paratethyan stratigraphy

The Miocene palaeogeographic evolution of the Paratethys Sea is still poorly constrained. Here, we use modern Mediterranean biochronology to provide an up‐to‐date overview of changing seas in Central Europe. Instead of a Paratethys that waxed and waned with fluctuating global sea levels, we show that the development of different seas was mainly controlled by tectonic phases. The Early Miocene “Ottnangian Sea” (~18 Ma) was connected to the Mediterranean via the Rhône valley, while the “Karpatian Sea” (~16.5 Ma) was initiated by a tectonically induced marine transgression through the Trans‐Tethyan gateway. In most Central European basins, the establishment of the “Badenian Sea” (<15.2 Ma), triggered by subduction‐related processes in the Pannonian and Carpathian domain, is significantly younger (by ~1 Myr) than usually estimated. The updated palaeogeographic reconstructions provide a better understanding of the concepts of basin dynamics, land–sea distribution and palaeoenvironmental change in the Miocene of Central Europe.     

Isotopic composition of dissolved inorganic carbon in subsurface sediments of gas hydrate-bearing mud volcanoes, Lake Baikal: implications for methane and carbonate origin

We report on the isotopic composition of dissolved inorganic carbon (DIC) in pore-water samples recovered by gravity coring from near-bottom sediments at gas hydrate-bearing mud volcanoes/gas flares (Malenky, Peschanka, Peschanka 2, Goloustnoe, and Irkutsk) in the Southern Basin of Lake Baikal. The δ¹³C values of DIC become heavier with increasing subbottom depth, and vary between ?9.5 and +21.4‰ PDB. Enrichment of DIC in ¹³C indicates active methane generation in anaerobic environments near the lake bottom. These data confirm our previous assumption that crystallization of carbonates (siderites) in subsurface sediments is a result of methane generation. Types of methanogenesis (microbial methyl-type fermentation versus CO₂-reduction) were revealed by determining the offset of δ¹³C between dissolved CH₄ and CO₂, and also by using δ¹³C and δD values of dissolved methane present in the pore waters. Results show that both mechanisms are most likely responsible for methane generation at the investigated locations.     

Effect of pH and organic ligands on the kinetics of smectite dissolution at 25 °C

Forward dissolution rates of Na-Montmorillonite (Wyoming) SWy-2 smectite (Ca_0.06Na_0.56)[Al_3.08Fe(III)_0.38Mg_0.54] [Si_7.93 Al_0.07]O₂₀(OH)₄ were measured at 25 °C in a mixed-flow reactor equipped with interior dialysis compartment (6-8 kDa membrane) as a function of pH (1-12), dissolved carbonate (0.5-10 mM), phosphate (10⁻⁵ to 0.03 M), and nine organic ligands (acetate, oxalate, citrate, EDTA, alginate, glucuronic acid, 3,4-dihydroxybenzoic acid, gluconate, and glucosamine) in the concentration range from 10⁻⁵ to 0.03 M. In organic-free solutions, the Si-based rates decrease with increasing pH at 1 ? pH ? 8 with a slope close to −0.2. At 9 ? pH ? 12, the Si-based rates increase with a slope of ∼0.3. In contrast, non-stoichiometric Mg release weakly depends on pH at 1 ? pH ? 12 and decreases with increasing pH. The empirical expression describing Si-release rates [R, mol/cm²/s] obtained in the present study at 25 °C, I = 0.01 M is given by

     

Endogenic heat from Enceladus' south polar fractures: New observations, and models of conductive surface heating

Linear features dubbed “tiger stripes” in the south polar region of Enceladus have anomalously high heat fluxes and are the apparent source of the observed plume. Several explanations for the observed activity have been proposed, including venting from a subsurface reservoir of liquid water, sublimation of surface ice, dissociation of clathrates, and shear heating. Thermal modeling presented in this work, coupled with observations from the Cassini Composite Infrared Spectrometer (CIRS) instrument, seeks to elucidate the underlying physical mechanism by constraining vent temperatures and thermal emission sources, using a model in which the observed thermal signature results primarily from conductive heating of the surface by warm subsurface fractures. The fractures feed surface vents, which may themselves contribute to the observed thermal emission. Model variables include vent temperature, presence of a surface insulating layer, vent width, time-variable heat input, and heat sources other than the central vent. Results indicate that CIRS spectra are best fitted with a model in which the surface is heated by narrow vents at temperatures as high as 223 K. Although equally good fits can be obtained for vent temperatures in the range of 130 to 155 K if the vents are wider (180 m and 22 m respectively) and dominate the emission spectrum, these models are probably less realistic because vents with these temperatures and widths cannot supply the observed H₂O vapor flux. The lack of emission angle dependence of the thermal emission when July 2005 and November 2006 CIRS observations are compared also argues against thermal emission being dominated by the vents themselves. Thus, results favor high-temperature models, possibly venting from a subsurface liquid water reservoir. However, a fracture filled with liquid water near the surface would produce significantly higher radiances than were detected unless masked by a thermally insulating surface layer. Models that best match the CIRS data are characterized by small fractions of the surface at high temperatures, which strengthens the case for the vents and/or their conductively-heated margins being the primary heat source. Models where the thermal emission is dominated by conductive heating of the surface from below by a laterally-extensive buried heat source cannot reproduce the observed spectrum. Models with a 10 cm thick upper insulating layer produce a poor match to the CIRS spectra, suggesting high thermal inertias near the tiger stripes. Finally, tiger stripe thermal emission measured by CIRS varied by less than 15% over the 16 month period from July 2005 to November 2006.     

Synthetic stellar and SSP libraries as templates for Gaia simulations

ESA’s Gaia mission will collect low resolution spectroscopy in the optical range for ～10⁹ objects. Complete and up-to-date libraries of synthetic stellar spectra are needed to built algorithms aimed to automatically derive the classification and the parametrization of this huge amount of data. In addition, libraries of stellar spectra are one of the main ingredients of stellar population synthesis models, aiming to derive the properties of unresolved stellar populations from their integrated light. We present (a) the newly computed libraries of synthetic spectra built by the Gaia community, covering the whole optical range (300–1100 nm) at medium-high resolution of (0.3 nm) for stars spanning the most different types, from M to O, from A-peculiar to Emission lines to White Dwarfs, and (b) the implementation of those libraries in our SSP code (Tantalo in The Initial Mass Function 50 Years Later, 327:235 2005), exploring different stellar evolution models.     

Numerical modeling of impact‐induced hydrothermal activity at the Chicxulub crater

Abstract— Large impact events like the one that formed the Chicxulub crater deliver significant amounts of heat that subsequently drive hydrothermal activity. We report on numerical modeling of Chicxulub crater cooling with and without the presence of water. The model inputs are constrained by data from borehole samples and seismic, magnetic, and gravity surveys. Model results indicate that initial hydrothermal activity was concentrated beneath the annular trough as well as in the permeable breccias overlying the melt. As the system evolved, the melt gradually cooled and became permeable, shifting the bulk of the hydrothermal activity to the center of the crater. The temperatures and fluxes of fluid and vapor derived from the model are consistent with alteration patterns observed in the available borehole samples. The lifetime of the hydrothermal system ranges from 1.5 to 2.3 Myr depending on assumed permeability. The long lifetimes are due to conduction being the dominant mechanism of heat transport in most of the crater, and significant amounts of heat being delivered to the near‐surface by hydrothermal upwellings. The long duration of the hydrothermal system at Chicxulub should have provided ample time for colonization by thermophiles and/or hyperthermophiles. Because habitable conditions should have persisted for longer time in the central regions of the crater than on the periphery, a search for prospective biomarkers is most likely to be fruitful in samples from that region.     

Complex geographical analysis of the Greater Sochi region on the Black Sea coast

Results of the complex analysis of the unique natural territory of Greater Sochi from the point of view of physical geography are considered. The region of Greater Sochi is located on the S slopes of the Main Caucasus chain on the eastern coast of the Black Sea. Morphometrical analysis of the relief and analysis air surface temperature and precipitation allowed to distinguish four specific subregions within the whole territory. It is demonstrated that the period of stable snow cover in the two subregions which occupy more than half of the region's area is sufficient for successful development of winter tourism. Peculiar combination of the mild climate of the coast with stable snow cover in the mountains till the beginning of summer provide strong attractivity of the region for all-the-year-round tourists inflow to the most modern recreational centre of Russia. The work provides the methodology for similar studies.     

Kinetics of brucite dissolution at 25°C in the presence of organic and inorganic ligands and divalent metals

Brucite (Mg(OH)₂) dissolution rate was measured at 25°C in a mixed-flow reactor at various pH (5 to 11) and ionic strengths (0.01 to 0.03 M) as a function of the concentration of 15 organic and 5 inorganic ligands and 8 divalent metals. At neutral and weakly alkaline pH, the dissolution is promoted by the addition of the following ligands ranked by decreasing effectiveness: EDTA ≥ H₂PO₄⁻ > catechol ≥ HCO₃⁻ > ascorbate > citrate > oxalate > acetate ∼ lactate and it is inhibited by boric acid. At pH >10.5, it decreases in the presence of PO₄³⁻, CO₃²⁻, F⁻, oxine, salicylate, lactate, acetate, 4-hydroxybenzoate, SO₄²⁻ and B(OH)₄⁻ with orthophosphate and borate being the strongest and the weakest inhibitor, respectively. Xylose (up to 0.1 M), glycine (up to 0.05 M), formate (up to 0.3 M) and fulvic and humic acids (up to 40 mg/L DOC) have no effect on brucite dissolution kinetics. Fluorine inhibits dissolution both in neutral and alkaline solutions. From F sorption experiments in batch and flow-through reactors and the analysis of reacted surfaces using X-ray Photoelectron Spectroscopy (XPS), it is shown that fluorine adsorption is followed by its incorporation in brucite lattice likely via isomorphic substitution with OH. The effect of eight divalent metals (Sr, Ba, Ca, Pb, Mn, Fe, Co and Ni) studied at pH 4.9 and 0.01 M concentration revealed brucite dissolution rates to be correlated with the water molecule exchange rates in the first hydration sphere of the corresponding cation.The effect of investigated ligands on brucite dissolution rate can be modelled within the framework of the surface coordination approach taking into account the adsorption of ligands on dissolution-active sites and the molecular structure of the surface complexes they form. The higher the value of the ligand sorption constant, the stronger will be its catalyzing or inhibiting effect. As for Fe and Al oxides, bi- or multidentate mononuclear surface complexes, that labilize Mg-O bonds and water coordination to Mg atoms at the surface, enhance brucite dissolution whereas bi- or polynuclear surface complexes tend to inhibit dissolution by bridging two or more metal centers and extending the cross-linking at the solid surface. Overall, results of this study demonstrate that very high concentrations of organic ligands (0.01-0.1 M) are necessary to enhance or inhibit brucite dissolution. As a result, the effect of extracellular organic products on the weathering rate of Mg-bearing minerals is expected to be weak.